Stability of the infinite layer structure with iron square planar coordination.
نویسندگان
چکیده
The recently discovered SrFeO2 prepared by a soft chemical route from a precursor SrFeO3 has the "infinite layer" (IL) structure with an unprecedented FeO4 square-planar coordination. We show that the IL structure has significant solubility to yield Sr1-xCaxFeO2 (0 <or= x <or= 1) and is thermally stable (at least as high as 1000 K for SrFeO2). These results demonstrate that the IL structure, once it is formed at low temperatures, is surprisingly robust owing to the extremely covalent nature of the Fe-O bond, thereby opening a door to chemical tuning of properties and to possible high-temperature applications.
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 130 12 شماره
صفحات -
تاریخ انتشار 2008